doodlexrays

00HOW CONSERVATORS LOOK INSIDE

The painting under
the painting.

A conservator in a museum studio studying a glowing X-ray film of an old portrait on a light box, with the framed painting on an easel beside it
AI-generated image, not a photograph of a real person or place.

An X-ray sees what the eye cannot.

Museum conservators X-ray paintings to see how they were built: the heavy lead white an artist laid down, a figure that was later painted out, a repaired tear, or a whole earlier picture on a reused canvas.

LEAD WHITEshows up brightUpdated

Test a pigment

01Principles

  • Heavy metals block X-rays
  • Changes of mind show through
  • Repairs cannot hide
  • Reading a painting from the inside

02THE SHORT ANSWER

Dense paint shows,
light paint vanishes.

An X-radiograph is a map of what absorbs X-rays.
In old paintings, that mostly means lead white.

HOW IT WORKS

Heavy atoms block the rays

Pigments made with metals of high atomic number absorb X-rays best. Lead white, the main white for centuries, is the strongest of all.

Test a pigment

WHAT IT FINDS

Two paintings in one

Artists sometimes reused canvases, so an X-ray can show an earlier picture underneath. A Whistler seaside landscape hides a vertical portrait.

See the numbers

WHY IT MATTERS

Repairs and changes of mind

X-rays spot repaired tears, holes in panels and cut-down edges, and can reveal pentimenti, the changes an artist made while painting.

How it is done

03A QUICK PIGMENT CHECK

How bright would it
look on an X-ray?

Pick a traditional pigment to see how strongly it absorbs X-rays. The bar shows how bright it tends to appear on the film: the more it blocks, the brighter it shows.

Based on the pigment absorption table in WebExhibits' Pigments through the Ages. Real images also depend on how thick the paint is and how much pigment it holds.

Pigment check

Choose a pigment
Lead whiteVery high

Lead has atomic number 82, so lead white blocks X-rays very strongly. It records the structure of most older paintings.

Zinc whiteHigh

Zinc (atomic number 30) absorbs well, though less than lead. The same table rates cadmium yellow and emerald green high too.

Red or yellow ochreMedium

Ochres owe their colour to iron (atomic number 26) and absorb only moderately, like umber, cobalt blue and Prussian blue.

Carmine lakeLow

An organic pigment based on carbon (atomic number 6). It lets most X-rays through and barely registers.

Carbon blackLow

Also carbon based, so it is among the weakest absorbers. A drawing in carbon black can be almost invisible on an X-ray.

Source: WebExhibits, Pigments through the Ages: X-ray light (absorption table and atomic numbers).

04TWO NUMBERS WORTH KNOWING

One element,
one discovery.

The number that makes lead white so visible,
and the year the rays were found.

Z = 82

Protons in a lead nucleus

Pigments made of lead, such as lead white, chrome yellow, Naples yellow and minium, block X-rays best. Carbon-based pigments, with atomic number 6, are the worst absorbers.

LEAD · ATOMIC NUMBER

1895

Year the rays were found

Wilhelm Röntgen noticed a faint glow on a nearby screen while studying cathode rays in 1895. He received the Nobel Prize in Physics in 1901 for the rays later named after him.

DISCOVERY · NOBEL PRIZE

Paintings are X-rayed at exposures far lower than medical X-rays, and WebExhibits notes the low dose does not harm or alter the painting materials.

05FOUR STEPS IN THE STUDIO

From painting
to radiograph.

X-radiography is not photography. It records how much of the beam each part of the painting stops, layer upon layer, all at once.

  1. Hold it by the edges

    The painting is held in a frame by its edges so nothing touches the paint surface.

  2. Film against the paint

    A sheet of radiographic film goes against the paint layer, where it gives the sharpest image of the artist's working.

  3. Beam from behind

    The X-ray tube sends its beam through the painting from beneath, onto the film.

  4. Stitch the sheets

    Each sheet is only a bit larger than a printer page, so large paintings need several, joined into one image with software.

Gloved hands holding a large X-ray film sheet up to the light, showing a ghostly image of a painted face
AI-generated image, not a photograph of a real person or place.

06X-RAY OR INFRARED?

Different rays,
different secrets.

Small glass jars of dry artists' pigment powders in white, yellow, red ochre and black on a wooden studio table
AI-generated image, not a photograph of a real person or place.

X-rays mostly show dense, metal-rich paint, so they are good at finding lead-white figures, repairs and reused supports. They see little of a carbon-black sketch.

Infrared reflectography is used to reveal underdrawing, the artist's first outline on the primed support. The Phillips Collection says infrared showed that Picasso's The Blue Room was painted over an earlier portrait of a man.

07Questions

Questions people ask

Why does lead white show up so clearly?

Lead has a high atomic number, 82, so it absorbs X-rays very well. Lead white was the principal white pigment for centuries, so it maps out much of an old painting's structure.

Can an X-ray find a hidden painting?

Yes, sometimes. Artists reused canvases and supports, and an X-ray can reveal the earlier picture. WebExhibits gives the example of a Whistler seaside landscape that conceals a vertical portrait.

What is a pentimento?

The National Gallery explains it comes from the Italian for repenting or changing your mind: a change the artist made while painting, usually hidden under later paint. X-rays and infrared can detect them.

Does X-raying damage a painting?

Paintings are X-rayed at exposures far lower than medical X-rays, and the low dose does not hurt or alter the materials. The operator needs protection, and facilities need licences.

Can X-rays help spot fakes?

They can show what an object is really made of. Forgers sometimes use a period panel or canvas, and an X-ray of a ceramic jug can show it was rebuilt from shards.

08Sources

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